Erm... aside from Link?
The man in the OoT room of all the jars. He's so stoic, I'd love to do a ton of ridiculous things in front of him just to make him crack.
Girahim, to help me make him crack and to just be his pal. How fabulous would that be?
Darunia, because he dances. "Oh! Whoa! Yeah, Baby!" He's shameless when the music comes. He could teach me a few things. And he's a goron.
Mikau, before he died of course, because he's a skilled song artist and he seems quite friendly. Everyone addresses him like a friend instead of a distant legend. He's also kinda hot for a Zora. Look at the character model, not the artwork.
Anjean, because of how she closes one eye all the time, is powerful but smart and very caring, and she may let me ride the Spirit Train. But maybe I should ask Engineer Link for that...
Which brings us to Engineer Link, because he did everything the other Links did, and he drives a train.
Ferrus. He takes pictures, he can walk across the kingdom in about an hour, and he's just plain awesome. Also, he like middle-of-nowhere-ish locations and he knows everything.
Oshus, because Oshus rocks.
Linebeck, because once he gets attached to you he'll do anything to protect you, and despite being a total coward, he's cool.
There's more, BTU I'll leave it there.